Analytical Sciences
Online ISSN : 1348-2246
Print ISSN : 0910-6340
ISSN-L : 0910-6340
Original Papers
Shape of the Liquid–Liquid Interface in Micro Counter-Current Flows
Arata AOTAAkihide HIBARAYasuhiko SUGIITakehiko KITAMORI
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2012 Volume 28 Issue 1 Pages 9

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Abstract
We investigated the shape of the liquid–liquid interface in micro counter-current flows formed within microchannels. The pressure balance at the interface was calculated based on the interface geometry. Although the shape should be an arc under laminar flow, a large deformation near the center of the microchannel was observed. In the center of the microchannel, Laplace pressure (171 – 450 Pa) was induced toward the aqueous phase. In contrast, near both sidewalls, Laplace pressure (81 – 166 Pa) was induced toward the organic phase. This result suggests that opposing flow occurs in the adjacent phases near the interface, with spiral-like flow generation.
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© 2012 by The Japan Society for Analytical Chemistry
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