Analytical Sciences
Online ISSN : 1348-2246
Print ISSN : 0910-6340
ISSN-L : 0910-6340
Original Papers
Nondestructive Quantitative Analysis of a Heavy Element in Solution or Suspension by Single-Shot Computed Tomography with a Polychromatic X-ray Source
Yoshito NAKASHIMATsukasa NAKANO
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Supplementary material

2012 Volume 28 Issue 12 Pages 1133-1138

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Abstract
X-ray computed tomography (CT) images obtained with a polychromatic X-ray source were simulated by computer for homogeneous solutions and suspensions containing a heavy element. When the K-edge of the element was near the peak energy of the polychromatic X-ray spectrum, the degree of beam hardening in the simulated CT image strongly depended on the atomic number and molar concentration of the heavy element. We analyzed the beam hardening of a single measured CT image of a CeCl3 aqueous solution sample, and successfully estimated the atomic number and the molar concentration of Ce simultaneously within a certain error. This single-shot, or single-energy (as opposed to dual-energy), CT method permits quick, nondestructive screening of a hazardous heavy element in a solution or suspension confined in a container.
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© 2012 by The Japan Society for Analytical Chemistry
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