Analytical Sciences
Online ISSN : 1348-2246
Print ISSN : 0910-6340
ISSN-L : 0910-6340
Original Papers
Poly(thymine)-templated Fluorescent Copper Nanoparticles for Ultrasensitive Label-free Detection of Pb2+ Ion
LiJuan OUXiaoYan LIHongWei LIULiJuan LIXia CHU
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2014 Volume 30 Issue 7 Pages 723-727

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Abstract
Polythymine (poly T)-templated copper nanoparticles (CuNPs) were demonstrated as novel and sensitive fluorescence probes for the detection of Pb2+ based on the fluorescence quenching effect. The as-prepared CuNPs displayed strong fluorescence emission. However, the fluorescence of CuNPs was readily quenched in the presence of Pb2+. These changes in fluorescence intensity of CuNPs allowed for the analysis of Pb2+ with rapidity (<10 min), simplicity (label-free), high sensitivity (LOD 0.4 nM), high selectivity (no interference from other metal ions) and at low-cost (without any labels and sophisticated operation). We validated the practicality of using CuNPs for the determination of Pb2+ in environmental samples through analyses of tap water samples.
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© 2014 by The Japan Society for Analytical Chemistry
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