Liquid-Liquid Extraction of Some Class b Metal Ions with Thiacrown Ether 1, 4, 8, 11-Tetrathiacyclotetradecane

Eiichi SEKIDO; Keiitsu SAITO; Yoshiaki NAGANUMA; Hiroko KUMAZAKI

doi:10.2116/analsci.1.363

Eiichi SEKIDO, Keiitsu SAITO, Yoshiaki NAGANUMA, Hiroko KUMAZAKI

Author information

Keywords: Liquid-liquid extraction, class b metals, thiacrown ethers, 1,4,8,11-tetrathiacyclotetradecane

JOURNAL FREE ACCESS

1985 Volume 1 Issue 4 Pages 363-368

DOI https://doi.org/10.2116/analsci.1.363

Details

Published: 1985 Received: May 27, 1985 Available on J-STAGE: June 13, 2006 Accepted: July 19, 1985 Advance online publication: - Revised: -
Correction information
Date of correction: June 13, 2006 Reason for correction: - Correction: CITATION Details: Wrong : 1). I. M. Kolthoff, Anal. Chem., 51, 1R-22R (1979).
2). D. Sevdic and H. Mieder, J. Inorg. Nucl. Chem., 39, 1403, 1409 (1977).
3). D. Sevic, L. Fekete and H. Mieder, J. Inorg, Nucl. Chem., 42, 885 (1980).
4). K. Saito, Y. Masuda and E. Sekido, Anal. Chim. Acta, 151, 447 (1984).
5). K. Saito, Y. Masuda and E. Sekido, Bull. Chem. Soc. Jpn., 57, 189 (1984).
6). W. Rosen and D. H. Busch, J. Am. Chem. Soc., 91, 4694 (1969).
7). J. F. J. Dippy, S. R. C. Hughes and J. W. Laxton, J. Chem. Soc., 1956, 2995.
8) .J. Bjerrum, G. Schwarzenbach and L. G. Sillen, "Stability Constants of Metal Ion Complexes with Solubility Products of Inorganic Substances" Part II, The Chemical Society, London (1957).
9). V. B. Pett, L. L. Diaddario Jr., E. R. Dockal, P. W. Corfield, C. C. Milton, D. Glick, L. A. Ochrymowycz and D. B. Rorabacher, Inorg. Chem., 22, 3661 (1983).
10). L. S. W. L. Sokol, L. A. Ochrymowycz and D. B. Rorabacher, Inorg. Chem., 20, 3189 (1981).
11). M. D. Glick, D. P. Gavel, L. L. Diaddario, Jr. and D. B. Rorabacher, Inorg Chem., 15, 1190 (1976).
12). L. Pauling "The Nature of the Chemical Bond" 3rd ed., Chapter 7, Cornell University Press, Ithaca, N. Y.,(1960).
13). E. R. Dockal, L. L. Diaddario and M. D. Rorabacher, J. Am. Chem. Soc., 99, 4530 (1977).
14). S. Yamada and M. Tanaka, J. Inorg. Nucl. Chem., 37, 587 (1975).
15). R. E. DeSimone and M. D. Glick, J. Am. Chem. Soc., 98, 768 (1976).
16). N. W. Alcock, N Herron and P. Moore, J. Chem. Soc. Dalton Trans., 1978, 394.

Right : 1). I. M. Kolthoff, Anal. Chem., 51, 1R-22R (1979).
2). D. Sevdic and H. Mieder, J. Inorg. Nucl. Chem., 39, 1403, 1409 (1977).
3). D. Sevic, L. Fekete and H. Mieder, J. Inorg, Nucl. Chem., 42, 885 (1980).
4). K. Saito, Y. Masuda and E. Sekido, Anal. Chim. Acta, 151, 447 (1984).
5). K. Saito, Y. Masuda and E. Sekido, Bull. Chem. Soc. Jpn., 57, 189 (1984).
6). W. Rosen and D. H. Busch, J. Am. Chem. Soc., 91, 4694 (1969).
7). J. F. J. Dippy, S. R. C. Hughes and J. W. Laxton, J. Chem. Soc., 1956, 2995.
8) .J. Bjerrum, G. Schwarzenbach and L. G. Sillen, "Stability Constants of Metal Ion Complexes with Solubility Products of Inorganic Substances" Part II, The Chemical Society, London (1957).
9). V. B. Pett, L. L. Diaddario Jr., E. R. Dockal, P. W. Corfield, C. C. Milton, D. Glick, L. A. Ochrymowycz and D. B. Rorabacher, Inorg. Chem., 22, 3661 (1983).
10). L. S. W. L. Sokol, L. A. Ochrymowycz and D. B. Rorabacher, Inorg. Chem., 20, 3189 (1981).
11). M. D. Glick, D. P. Gavel, L. L. Diaddario, Jr. and D. B. Rorabacher, Inorg Chem., 15, 1190 (1976).
12). L. Pauling "The Nature of the Chemical Bond" 3rd ed., Chapter 7, Cornell University Press, Ithaca, N. Y.,(1960).
13). E. R. Dockal, L. L. Diaddario and M. D. Rorabacher, J. Am. Chem. Soc., 99, 4530 (1977).
14). S. Yamada and M. Tanaka, J. Inorg. Nucl. Chem., 37, 587 (1975).
15). R. E. DeSimone and M. D. Glick, J. Am. Chem. Soc., 98, 768 (1976).
16). N. W. Alcock, N Herron and P. Moore, J. Chem. Soc. Dalton Trans., 1978, 394.

Date of correction: June 13, 2006 Reason for correction: - Correction: PDF FILE Details: -

Abstract

Liquid-liquid extraction of some class b metals, silver(I), mercury(II), palladium(II) and cadmium(II) using thiacrown compound, 1, 4, 8, 11-tetrathiacyclotetradecane(TTCT) and picrate(Pic^-) was stoichiometrically examined. Silver(I) and mercury(II) are extracted into 1, 2-dichloroethane as ion-pair compounds, [Ag(ttct)₂]⁺Pic^- and [Hg-(ttct)]²⁺Pic₂^- respectively. Palladium(II) is extracted into nitrobenzene as [Pd(ttct)]²⁺Pic₂^- or [Pd(ttct)₂] ²⁺Pic₂^- depending on the concentration ratio of TTCT to palladium(II). The extraction constants for silver(I) and mercury(II) and also the distribution coefficient of TTCT in various solvents were determined. The extraction behaviors of these class b metals including copper(I) were compared and discussed in connection with the composition and the conceivable conformation of their extracts.

Corresponding author

Correction information

Register with J-STAGE for free!