Analytical Sciences
Online ISSN : 1348-2246
Print ISSN : 0910-6340
ISSN-L : 0910-6340
Determination of the Pesticide Carbaryl by Microemulsion Room-Temperature Phosphorescence in Real Samples
Antonio SEGURA CARRETEROCarmen CRUCES BLANCOAlberto FERNÁNDEZ GUTIÉRREZ
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1996 Volume 12 Issue 4 Pages 653-657

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Abstract
A room-temperature phosphorescence method for the determination of the pesticide carbaryl is described. The proposed method is based on the formation of a microemulsion obtained by mixing an apolar solvent with the surfactant sodium dodecyl sulfate as the micellar medium in the presence of thallium nitrate as the external heavy atom salt. To avoid the oxygen quenching, a sodium sulfite solution was used. A complete and exhaustive statistical analysis of experimental data by a multivariate optimization approach was performed to establish the optimum experimental variables. Good results have been obtained when the insecticide have been analyzed in synthetic and real samples.
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© The Japan Society for Analytical Chemistry
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