Gas Chromatographic Analysis of Atmospheric Sulfur Compounds Using Cryogenic Sampling and A Modified Thermal Desorber

Y.C. CHEN; J.G. Lo

doi:10.2116/analsci.13.Supplement_199

Y.C. CHEN, J.G. Lo

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Keywords: Thermal desorption, sulfur chemiluminescence detector

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1997 Volume 13 Issue Supplement Pages 199-204

DOI https://doi.org/10.2116/analsci.13.Supplement_199

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Published: 1997 Received: - Available on J-STAGE: July 07, 2006 Accepted: - Advance online publication: - Revised: -
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Date of correction: July 07, 2006 Reason for correction: - Correction: CITATION Details: Wrong : 1). A. Tangerman, J. Chromatogr., 366, 205 (1986)
2). J. Namiesnik,, Talanta, 35, 567 (1988).
3). M.S. Black, R.P Herbst and D.R. Hitchcock,, Anal. Chem., 50, 848 (1978)
4). Kangas Juhani and Ryosa Hannus, Chemosphere, 17, 905 (1988).
5). A. Przyjazny, J. Chromatogr., 333, 327 (1985).
6). P.A. Steudler and W. Kijowski, Anal. Chem. 56, 1432-1436 (1984).
7). S.O. Farwell, S.J. Gluck, W.L. Bamesberger, T.M. Schutte and D.F. Adams, Anal. Chem., 51, 609 (1979).
8). W.E. Beard and W.D. Guenzi, J. Environ. Qual., 12, 113 (1983).
9). F.J. Sandalls and S.A. Penkett, Atmos. Environ., 11, 197 (1977).
10). P.A. Steudler and W. Kijowski, Anal. Chem., 56, 1432 (1984).
11). R. L. Benner and D..H. Stedman, Anal. Chem., 61, 1268 (1989).
12). K.K. Gaines, W.H. Chatham and S.O. Farwell, HRC.CC., 13, 489 (1990).
13). F.P. Di Sanzo, W. Bray and B. Chawla, HRC.CC., 17, 255 (1994).
14). R.H. Brown and C.J. Purnell, J. Chromatogr., 178, 19 (1979).
15). K Grob Jr., G. Karrer and M. L. Riekkola, J. Chromatogr., 334, 129 (1985).

Right : 1). A. Tangerman, J. Chromatogr., 366, 205 (1986)
2). J. Namiesnik,, Talanta, 35, 567 (1988).
3). M.S. Black, R.P Herbst and D.R. Hitchcock,, Anal. Chem., 50, 848 (1978)
4). Kangas Juhani and Ryosa Hannus, Chemosphere, 17, 905 (1988).
5). A. Przyjazny, J. Chromatogr., 333, 327 (1985).
6). P.A. Steudler and W. Kijowski, Anal. Chem. 56, 1432-1436 (1984).
7). S.O. Farwell, S.J. Gluck, W.L. Bamesberger, T.M. Schutte and D.F. Adams, Anal. Chem., 51, 609 (1979).
8). W.E. Beard and W.D. Guenzi, J. Environ. Qual., 12, 113 (1983).
9). F.J. Sandalls and S.A. Penkett, Atmos. Environ., 11, 197 (1977).
10). P.A. Steudler and W. Kijowski, Anal. Chem., 56, 1432 (1984).
11). R. L. Benner and D..H. Stedman, Anal. Chem., 61, 1268 (1989).
12). K.K. Gaines, W.H. Chatham and S.O. Farwell, HRC.CC., 13, 489 (1990).
13). F.P. Di Sanzo, W. Bray and B. Chawla, HRC.CC., 17, 255 (1994).
14). R.H. Brown and C.J. Purnell, J. Chromatogr., 178, 19 (1979).
15). K Grob Jr., G. Karrer and M. L. Riekkola, J. Chromatogr., 334, 129 (1985).

Date of correction: July 07, 2006 Reason for correction: - Correction: PDF FILE Details: -

Abstract

A refined cryogenic sampling method and a modification of a commercialized thermal desorber for automatic analysis of atmospheric sulfur compounds with a gas chromatography coupled to the sulfur chemiluminescence detector is reported. Twenty eight reduced sulfur compounds were analyzed on a 30mx0.32mm i.d., 4μm film thickness, Quadrex 007 series (dimethyl silicon phase) capillary column. The problems of retention time shift and peak splitting caused by the water were significantly improved by connecting a 70-cm deactivated column before the analytical column. For one-liter air sample with 80% relative humidity at 30°C, the retention time shift can be diminished to 1% for the compounds with boiling point higher than ethanethiol.

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