Determination of Trace Aluminum in Natural Waters by Ion Exchanger Fluorometry

Fermin CAPITAN; Eloisa MANZANO; Jose Luis VILCHEZ; Luis Fermin CAPITAN-VALLVE

doi:10.2116/analsci.5.549

Fermin CAPITAN, Eloisa MANZANO, Jose Luis VILCHEZ, Luis Fermin CAPITAN-VALLVE

Author information

Keywords: Ion-exchanger fluorometry, aluminum determination, natural waters

JOURNAL FREE ACCESS

1989 Volume 5 Issue 5 Pages 549-555

DOI https://doi.org/10.2116/analsci.5.549

Details

Published: October 10, 1989 Received: January 30, 1989 Available on J-STAGE: June 30, 2006 Accepted: June 28, 1989 Advance online publication: - Revised: -
Correction information
Date of correction: June 30, 2006 Reason for correction: - Correction: CITATION Details: Wrong : 1). A. Fernandez Gutierrez and A. Muñoz de la Peña, in "Molecular Luminiscence Spectroscopy: Methods and Applications"; ed. S. G. Schulman, Part I, Chap. 4, John Wiley, New York, 1985.
2). M. Katyal, Talanta, 15, 95 (1968).
3). F. Hernadez Hernandez and J. Medina Escriche, Quim. Anal., 5, 1 (1986).
4). C. E. White, H. C. E. McFarlane, F. Fogt and R. Fuchs, Anal. Chem., 39, 367 (1967).
5). M. J. Blanch, Thesis, GR-399-1986, University of Granada, Spain, 1986.
6). H. Waki, S. Noda and M. Yamashita, Reactive Polymers, 7, 227 (1988).
7). F. Capitán, A. Navalón, J. L. Vilchez and L. F. Capitán-Vallvey, Talanta, in press.
8). F. Capitán, E. Manzano, A. Navalón, J. L. Vilchez and L. F. Capitán-Vallvey, Analyst [London], 114, 969 (1989).
9). R. J. Hurtubise, "Trace Analysis by LuminescenceSpectroscopy", in "Trace Analysis, Spectroscopic Methods for Molecules"; ed. G. D. Christian and B. Callis, Vol. 84, Chemical Analysis Series, John Wiley & Sons, New York, 1986.
10). K. Yoshimura and H. Waki, Talanta, 32, 345 (1985).
11). H. A. Laitinen and P. Kivalo, Anal. Chem., 24, 1467(1952).
12). "Standard Methods for the Examination of Water and Wastewater", APHA-AWWA-WPCF, 15th ed., 1980.
13). C. E. White and C. S. Lowe, Ind. End. Chem.; Anal. Ed., 12, 229 (1940).
14). L. A. Saarl and W. R. Seltz, Anal. Chem., 55, 667 (1983).
15). F. Hernandez Hernandez and J. Medina. Escriche, Analyst [London], 109, 1585 (1984).
16). F. Will, Anal. Chem., 33, 1360 (1961).
17). M. H. Fletcher, Anal. Chem., 37, 550 (1965).
18). Z. G. Szabo and M. T. Beck, Acta Chim. Acad. Sci. Hung., 4, 211 (1954).
19). N. L. Olenovich, L. I. Koval′chuk and R. F. Zufman, Zh. Anal. Khim., 28, 1939 (1973).
20). M. Katyal and S. Prakash, Talanta, 24, 367 (1986).
21). F. Garcia-Sanchez and C. Cruces-Blanco, Anal. Chem., 58, 73 (1986).
22). K. Watanabe, H. Yoshizawa and K. Kawagaki, Bunseki Kagaku, 30, 640 (1981).
23). R. L. Wilson and J. D. Ingle, jr., Anal. Chim. Acta, 92, 417 (1977).
24). K. Morishige, J. Inorg. Nucl. Chem., 40, 843 (1978).
25). L. A. Demina, O. M. Petrukhin, Yu. A. Zolotov and G. V. Serebryakova, Zh. Anal. Khim., 27, 1731 (1972).
26). K. Morishige, Anal. Chim. Acta, 121, 301 (1980).
27). K. Morishige, Anal. Chim. Acta, 72, 295 (1974).
28). J. M. Escriche and F. H. Hernandez, Analyst [London], 110, 287 (1985).
29). K. Morishige, J. Inorg. Nucl. Chem., 40, 843 (1978).

Right : 1). A. Fernandez Gutierrez and A. Muñoz de la Peña, in "Molecular Luminiscence Spectroscopy: Methods and Applications"; ed. S. G. Schulman, Part I, Chap. 4, John Wiley, New York, 1985.
2). M. Katyal, Talanta, 15, 95 (1968).
3). F. Hernadez Hernandez and J. Medina Escriche, Quim. Anal., 5, 1 (1986).
4). C. E. White, H. C. E. McFarlane, F. Fogt and R. Fuchs, Anal. Chem., 39, 367 (1967).
5). M. J. Blanch, Thesis, GR-399-1986, University of Granada, Spain, 1986.
6). H. Waki, S. Noda and M. Yamashita, Reactive Polymers, 7, 227 (1988).
7). F. Capitán, A. Navalón, J. L. Vilchez and L. F. Capitán-Vallvey, Talanta, in press.
8). F. Capitán, E. Manzano, A. Navalón, J. L. Vilchez and L. F. Capitán-Vallvey, Analyst [London], 114, 969 (1989).
9). R. J. Hurtubise, "Trace Analysis by LuminescenceSpectroscopy", in "Trace Analysis, Spectroscopic Methods for Molecules"; ed. G. D. Christian and B. Callis, Vol. 84, Chemical Analysis Series, John Wiley & Sons, New York, 1986.
10). K. Yoshimura and H. Waki, Talanta, 32, 345 (1985).
11). H. A. Laitinen and P. Kivalo, Anal. Chem., 24, 1467(1952).
12). "Standard Methods for the Examination of Water and Wastewater", APHA-AWWA-WPCF, 15th ed., 1980.
13). C. E. White and C. S. Lowe, Ind. End. Chem.; Anal. Ed., 12, 229 (1940).
14). L. A. Saarl and W. R. Seltz, Anal. Chem., 55, 667 (1983).
15). F. Hernandez Hernandez and J. Medina. Escriche, Analyst [London], 109, 1585 (1984).
16). F. Will, Anal. Chem., 33, 1360 (1961).
17). M. H. Fletcher, Anal. Chem., 37, 550 (1965).
18). Z. G. Szabo and M. T. Beck, Acta Chim. Acad. Sci. Hung., 4, 211 (1954).
19). N. L. Olenovich, L. I. Koval′chuk and R. F. Zufman, Zh. Anal. Khim., 28, 1939 (1973).
20). M. Katyal and S. Prakash, Talanta, 24, 367 (1986).
21). F. Garcia-Sanchez and C. Cruces-Blanco, Anal. Chem., 58, 73 (1986).
22). K. Watanabe, H. Yoshizawa and K. Kawagaki, Bunseki Kagaku, 30, 640 (1981).
23). R. L. Wilson and J. D. Ingle, jr., Anal. Chim. Acta, 92, 417 (1977).
24). K. Morishige, J. Inorg. Nucl. Chem., 40, 843 (1978).
25). L. A. Demina, O. M. Petrukhin, Yu. A. Zolotov and G. V. Serebryakova, Zh. Anal. Khim., 27, 1731 (1972).
26). K. Morishige, Anal. Chim. Acta, 121, 301 (1980).
27). K. Morishige, Anal. Chim. Acta, 72, 295 (1974).
28). J. M. Escriche and F. H. Hernandez, Analyst [London], 110, 287 (1985).
29). K. Morishige, J. Inorg. Nucl. Chem., 40, 843 (1978).

Date of correction: June 30, 2006 Reason for correction: - Correction: PDF FILE Details: -

Abstract

Morin (2′, 3, 4′, 5, 7-pentahydroxyflavone) has been used as a ligand in the fluorometric microdetermination of aluminum at the sub-μgl^-1 level. A method has been developed which is based on ion exchanger fluorometry (IEF). The 1:1 aluminum-morin complex is fixed on a dextran-type cationic exchanger, and the fluorescence of the gel, packed on a 1-mm quartz cell, is measured directly using a solid-surface attachment. The concentration for the method ranges between 0.4 and 1.6μgl^-1, although this can be diminished by increasing the sample volume. The method has been successfully applied to the determination of aluminum in natural water and offers several advantages in comparison with solution methods.

Corresponding author

Correction information

Register with J-STAGE for free!