Quantitative Studies of the Internal Referencing Method with the Bulbed Capillary External Referencing Method for Proton Nuclear Magnetic Resonance Spectroscopy

Kozo MOMOKI; Yoshiyuki FUKAZAWA

doi:10.2116/analsci.7.403

Kozo MOMOKI, Yoshiyuki FUKAZAWA

Author information

Keywords: Bulbed capillary external referencing method, internal referencing method, quantitative solute-solvent effect data, nuclear magnetic resonance

JOURNAL FREE ACCESS

1991 Volume 7 Issue 3 Pages 403-409

DOI https://doi.org/10.2116/analsci.7.403

Details

Abstract

Serious methodological defects of the internal referencing method are revealed by quantitative studies using the bulbed capillary external referencing method. Entirely new quantitative data on solute-solvent effects fatally affecting the internal referencing method are presented and discussed. Possibilities of new solute-solvent effect studies are also suggested.

Corresponding author

Register with J-STAGE for free!