抄録
A dinuclear piperazine-bridged (6,8,15,17-tetramethyldibenzo[b,i][1,4,8,11]tetraaza-cyclotetradecinato)zinc(II) complex was synthesized and characterized by X-ray crystallography. The complex crystallizes in triclinic crystal system under the space group P1 (#2) and Z = 1 with a = 11.700(1)Å, b = 12.908(1)Å, c = 9.607(1)Å, α = 102.787(9)°, β = 111.273(8)°, γ = 64.431(7)°, V = 1216.0(2)Å3. The bridging piperazine keeps its chair conformation and the two nitrogen atoms in the para positions of the six-member ring coordinate to zinc(II) atoms to form a dinuclear complex.
