抄録
The title complex [Ni(phen)2(H2O)Cl]Cl·H2O·CH3CN (phen = 1,10-phenanthroline) has been synthesized in solid phase reaction and characterized by X-ray diffraction analysis. The Ni(II) center is six-coordinated in a distorted octahedral geometry. The complexes form a dimeric structure through the two O-H…Cl hydrogen bonds, and neighboring π-π interactions link the dimer segments into a quasi-two-dimensional structure.
