Abstract
The structure of tris(diethylthiourea)bromosilver(I), [Ag(detu)3Br], is in a triclinic system space group P1 with the cell parameters a = 9.2072(7), b = 12.8854(10), c = 13.1900(10)Å, α = 63.5210(10), β = 71.8110(10), γ = 76.571(2)°, Z = 2, Dx = 1.467 g/cm3, V = 1322.70(18)Å3 and T = 293 K. The structure was refined to the final R1 = 0.0524 using all 5386 observed reflections. The complex is monomeric covalent with Ag atom bonded to three detu molecules and one Br atom. The geometry around Ag atom is tetrahedral.