Part 7
Crystal Structure of Gua4[Cu2(Cit)2] {Gua = Guanidinium, Cit = Citrate = 2-hydroxo-1,2,3-tricarboxylatopropane}
2007 年 23 巻 p. x123-x124
詳細
2007 年 23 巻 p. x123-x124
The title complex has been synthesized and structurally characterized by single-crystal X-ray diffraction. This complex has a dinuclear structure where two copper(II) ions are bridged by two bent alkoxo groups. The citrate acts as a tetradentate ligand coordinating via three carboxylates and an alkoxo groups in which one of three carboxylates is coordinated weakly. The coordination geometry around the Cu(II) is strongly distorted square pyramidal. The distance between the two copper atoms is 2.8386(3)Å.
