Synthesis and Crystal Structure of Bis(1,10-phenanthroline-5,6-dione)rhodium(I) Hexafluorophosphate, [Rh(phen-dione)2]PF6

Seyedeh Raziyeh HOSSEINIAN; S. Jamil A. FATEMI; Hassan HADADZADEH; Matthias WEIL; Aliakbar Dehno KHALAJI

doi:10.2116/analscix.24.x287

Part 12

Synthesis and Crystal Structure of Bis(1,10-phenanthroline-5,6-dione)rhodium(I) Hexafluorophosphate, [Rh(phen-dione)₂]PF₆

Seyedeh Raziyeh HOSSEINIAN, S. Jamil A. FATEMI, Hassan HADADZADEH, Matthias WEIL, Aliakbar Dehno KHALAJI

Author information

JOURNAL FREE ACCESS

2008 Volume 24 Pages x287-x288

DOI https://doi.org/10.2116/analscix.24.x287

Details

Abstract

The title compound, [Rh(phen-dione)₂]PF₆, where phen-dione is 1,10-phenanthroline-5,6-dione, crystallizes in the monoclinic space group P2₁/c (no. 14), with a = 9.5859(4)Å, b = 17.6272(8)Å, c = 13.5252(6)Å, β = 91.025(1)°, V = 2285.02(17)Å³, Z = 4, T = 100 K, R(F) = 0.0329, wR(F²) = 0.0894. The coordination polyhedron about the Rh(I) atom is a distorted [RhN₄] bisphenoid with two independent phen-dione as ligands.

Corresponding author

Register with J-STAGE for free!