The Journal of Antibiotics
Online ISSN : 1881-1469
Print ISSN : 0021-8820
ISSN-L : 0021-8820
THE CHEMISTRY OF LEUCOMYCINS. VI
STRUCTURES OF LEUCOMYCIN A4, A5, A6, A7, A8 AND A9
SATOSHI OMURAMICHIKO KATAGIRITOJU HATA
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ジャーナル フリー

1968 年 21 巻 4 号 p. 272-278

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抄録
Studies on the structures of new components of leucomycin, A4(IV), A5(III), A6(VI), A7(V), A8(VIII) and A9(VII), were carried out in parallel with those on components A1(I) and A3(II), namely acetylation, and acid and alkaline hydrolysis. The pairs of components IV and III, VIandV, and VIIand VIII gave respectively, acetates X, XI and XIII. Components IV, VI and VIII had then respectively, 4-O-n-butyryl-, 4-O-propionyl- and 4-O-acetyl-mycarose replacing the 4-O-isovaleryl mycarose in the A3. Like A3, components IV, VI and VII had an O-acetyl group on C-3 of the 16-membered lactone.
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© Japan Antibiotics Research Association
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