抄録
Chromatographic measurements were made for the adsorption of benzene, toluene and m-xylene on molecular sieving carbon (MSC) in supercritical fluid CO2 mixed with organics. Supercritical chromatograph packed with MSC was used to detect pulse responses of organics. Adsorption equilibria and adsorption dynamics parameters for organics were obtained by moment analysis of the response peaks. Dependences of adsorption equilibrium constants, K*, and micropore diffusivity, D, on the amount adsorbed were examined. The dependencies of adsorption equilibrium constants, K*, and micropore diffusivity, D, of toluene, benzene and m-xylene, on molarity of toluene with each parameters of temperature or pressure were obtained. It was found that the values of K* and D for an organic substance depended on the amount adsorbed of other organics strongly. And, molecular simulation of multicomponent adsorption equilibria was performed, and potential parameters were determined by comparing the simulation with experimental results. Simulation software is Cerius2 (Version4.2) made by MSI. The purpose of performing simulation is to elucidate an adsorption mechanism on the molecule level. As for the amount adsorbed, especially in DREIDING2.11, the simulation shows the value near experiment.
