Magnets for this Millennium Based Upon Coordination Compounds and New Coordination Chemistry

Joel S. Miller

doi:10.4019/bjscc.79.38

Bulletin of Japan Society of Coordination Chemistry

Online ISSN : 1883-1737
Print ISSN : 1882-6954
ISSN-L : 1882-6954

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Magnets for this Millennium Based Upon Coordination Compounds and New Coordination Chemistry

Joel S. Miller

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Keywords: Magnetism, magnetic ordering, extended framework structures, crystal field theory, Prussian blue, artificial antiferromagnet, pressure

JOURNAL FREE ACCESS

2022 Volume 79 Pages 38-49

DOI https://doi.org/10.4019/bjscc.79.38

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Abstract

Numerous coordination compounds have recently been identified exhibit the technologically important property of bulk magnetic ordering as ferro-, ferri- and antiferromagnets. These compounds range from the ionic [Fe(C₅Me₅)₂]⁺[TCNE]^.- (TCNE = tetracyanoethylene) ferromagnet to 3-D extended coordination network ferrimagnets. Additionally, many magnetically ordered percyanometallates are summarized. This Award presentation covers new magnetically ordered coordination compounds with an emphasis on new coordination chemistry that were discovered and studied in our laboratory.

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