2004 Volume 59 Issue 7 Pages 467-471
The filled-skutterudite PrOS4Sb12 has been attracting much attention because of the fact this is the only Pr-based heavy-fermion superconductor. Our muon spin relaxation measurements have revealed spontaneous appearance of static internal magnetic fields below the superconducting transition temperature. This observation provides unambiguous evidence for "the breaking of time-reversal symmetry" in the superconducting state.