Pharmaceutical Bulletin
Online ISSN : 1881-1345
Print ISSN : 0369-9471
ISSN-L : 0369-9471
Studies on Phenazines. XI. Nitration of Phenazine and Its Derivatives.(2)
Hirotaka Otomasu
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1956 Volume 4 Issue 2 Pages 117-120

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Abstract
1) The main product of m.p. 204°, which was previously obtained by the nitration of phenazine N-oxide, was converted into 3-methoxyphenazine 5-oxide by refluxing with methanolic solution of potassium hydroxide. 2) 1-and 2-Chlorophenazine were not nitrated with conc. sulfuric acid and potassium nitrate, even when the temperature was raised to 80°. 3) 1-, 2-, and 3-Chlorophenazine 5-oxides were substituted at the same 7-position by the nitro group.
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