Pharmaceutical Bulletin
Online ISSN : 1881-1345
Print ISSN : 0369-9471
ISSN-L : 0369-9471
Rearrangement Reaction of Picolyl Ethers with Sodium Amide. II.
Ikuo Suzuki
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JOURNAL FREE ACCESS

1956 Volume 4 Issue 6 Pages 479-482

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Abstract
Allylpyridylcarbinols (α or γ) were obtained from allyl picolyl ethers (α or γ) by the application of sodium amide in benzene. When the same reactions was carried out in xylene at 130∼140°, the yield of rearrangement product increased in the γ-compound, while a non-viscous oil was obtained from the α-compound. This non-viscous oily product was found to be identical with propyl α-pyridyl ketone.
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© The Pharmaceutical Society of Japan
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