PBb06 液晶化合物の自然光学分割

抄録

Syntheses of compounds having an asymmetric carbon atom involve a process of either elimination or addition that offer racemates. But, 3,5-difuluoro-1[4-(trans-4-propyl-cyctohexyl)cyclohexen-l-yl]benzene, synthesized from bicyclohexanone and Grignard reagent followed by simple recrystallization, showed Cholesteric phase. We are now studying the evidence of spontaneous enantiometric resolution of this compound.