日本液晶学会討論会講演予稿集
Online ISSN : 2432-5988
Print ISSN : 1880-3490
ISSN-L : 1880-3490
2000年 日本液晶学会討論会
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PBbl9 長鎖エチレンオキシド基を有するフェルラ酸誘導体のエステル化反応に伴う生成物の液晶性
杉野 卓司高森 愛物部 浩達*清水 洋
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p. 329-330

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A ferulic acid derivative which has a long ethyleneoxide group was obtained via esterification reaction from a oxyethylene-substituted ferulic acid and 4-cyano-4'-hydroxybiphenyl. The compound was identified with an adduct of esterificated ferulic acid derivative and N, N'-dicyclohexylcarbodiimide (DCC) used in the esterification reaction by the NMR. This compound showed a nematic phase and some other phases as well on cooling under the polarized microscopy experiments. The phase transition behaviour was complicated induced by thermal dissociation of the adduct. A single crystal was obtained by recrystallization from acetone to investigate the structure of the adduct.
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© 2000 日本液晶学会
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