日本液晶学会討論会講演予稿集
Online ISSN : 2432-5988
Print ISSN : 1880-3490
ISSN-L : 1880-3490
2002年 日本液晶学会討論会
セッションID: 3B01
会議情報

3B01 高分子-液晶混合系の界面張力(生体関連・リオトロピック液晶)
*松山 明彦
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抄録
We theoretically study interfacial properties between two coexisting phases in mixtures of a flexible polymer and a low molecular weight liquid crystal. By numerically solving Euler equations for compositional and orientational order parameter fields, we calculate the order parameter profiles and interfacial tensions for nematic-isotopic and isotropic-isotropic phase equilibria. We find that the order parameter profiles are non-monotonic at some temperatures. The nematic-isotopic interfacial tension increases with decreasing temperature and is approximately proportional to (T - T_<NI>)^n at temperatures below the nematic-isotropic transition temperature (T_<NI>) of the pure nematogen. The value of the exponent n is strongly affected by the existence of a triple point.
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© 2002 日本液晶学会
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