Proceedings of Japanese Liquid Crystal Society Annual meeting
Online ISSN : 2432-5988
Print ISSN : 1880-3490
ISSN-L : 1880-3490
2011 Japanese Liquid Crystal Society Annual Meeting
Session ID : 3b02
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Chirality Control of Aromatic Conjugated Polymers in Thermally Helicity-Controllable Asymmetric Liquid Crystal Reaction Field
*Sangbum Ahn, Munju Goh, Masaharu Yamamoto, Kazuyoshi Watanabe, Kazuo Akagi
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Keywords: asymmetric liquid crystal reaction fieald, chirallity control, helical structure, conjugated polymers
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Abstract
Chiral [poly(bithienylenephenylene), PBTP] derivatives were synthesized through the polycondensations of achiral monomers in thermally helicity-controllable chiral nematic liquid crystal (N∗-LC) reaction field. The thermally helicity-controllable N∗-LC provided us with two kinds of helically π-stacked structures conjugated polymers with opposite helical sense depending on the polymerization temperature.
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© 2011 Japanese Liquid Crystal Society
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