吸湿性シロキサンフォトポリマーを用いた界面活性剤ナノ構造の制御

抄録

A polysiloxane containing hygroscopicity and photocrosslinkable group was synthesized by sol-gel reaction of alkoxysilane. Spincast films consisting of polysiloxane and surfactant were prepared onto glass substrates. Then, by using humidity-controlled GI-XRD measurements, we can control the self-assembled nanostructures in the polysiloxane films. The nanostructures can also be fixed by photo-initiated thiol-ene reaction. In addition, the development into a porous material was attempted by removing the surfactant, suggesting the existence of porous nanostructure.