Proceedings of Japanese Liquid Crystal Society Annual meeting
Online ISSN : 2432-5988
Print ISSN : 1880-3490
ISSN-L : 1880-3490
2021 Japanese Liquid Crystals Conference
Session ID : PF03
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Stability of highly ordered smectic phases induced by Charge-Transfer Interaction
*Fujioka MitsukiTakei ShoyoShimada YudaiTabe Yuka
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Abstract

When two LC compounds working as an electron donor and acceptor are mixed, due to the charge-transfer interaction, they often exhibit highly ordered smectic phases such as SmE and SmB. In this report, we mixed 8CB and dialkyl-terminated azobenzene derivatives with the chain lengths of 8, 9, 10, and investigated how the molecular lengths should affect the phase diagrams of the mixtures. Among the three combinations, the mixtures of 8CB and 4,4'-di-n-octyl-azobenzene (8AB8) exhibited SmE phase in the largest range of mixing ratio. Since the lengths of 8CB-dimer and 8AB8 are close to each other, the length matching may play an important role in the stabilization of SmE phase.

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© 2021 The Japanese Liquid Crystal Society
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