液晶討論会講演予稿集
Online ISSN : 2432-9959
Print ISSN : 1880-3539
ISSN-L : 1880-3539
第22回 液晶討論会
セッションID: 1C06
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光学活性な置換基を有する1-アリール-2-シクロヘキシル-1,2-ジフルオロエチレンの合成と性質
井上 誠一本田 清*菊地 俊光小池 毅横小路 修
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会議録・要旨集 フリー

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抄録
(E)-1-Aryl-2-cyclohexyl-1,2-difluoroethylenes with optically active side chain were examined in purpose of application as chiral additive for STN liquid crystal devices. These compounds were derived from the optically active alcohols or carboxylic acids. Ether type compounds were synthesized from optically active alkoxyphenyllithium and 4-alkylcyclohexyltrifluoroethylene. Ester type compounds were obtained from the trifluoroethylene compound with p-bromophenyllithium or p-t-butyldimethylsilyloxyphenyllithium, respectively, followed by esterification.
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© 1996 一般社団法人日本液晶学会
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