液晶討論会講演予稿集
Online ISSN : 2432-9959
Print ISSN : 1880-3539
ISSN-L : 1880-3539
第23回 液晶討論会
セッションID: 2AC07
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側鎖型液晶性ポリシロキサンの相転移とレオロジー挙動
*田中 克史大岩 康孝笹岡 正幸久保野 敦史秋山 隆一
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Temperature dependence of the viscosity for a neat sample of a side-chain-type liquid crystalline polysiloxane (LCS) was measured from the isotropic phase to the liquid crystalline phase. At temperatures much higher than the isotropic - liquid crystalline phase transition temperature (Tc) measured by a polarized optical microscope, the viscosity was almost independent of the shear rate, and it increased as the temperature decreased. At temperatures slightly higher than Tc the viscosity measured at shear rates of 3Os-1 and 5Os-1 decreased steeply as the temperature decreased. These results were discussed in terms of the shear-induced ordering of mesogens of the LCS even at the temperatures above Tc.
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© 1997 一般社団法人日本液晶学会
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