液晶討論会講演予稿集
Online ISSN : 2432-9959
Print ISSN : 1880-3539
ISSN-L : 1880-3539
第23回 液晶討論会
セッションID: 1AC08
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液晶性を有する導電性ポリチエニレンの合成と性質
*豊島 良一柴田 諭尾坂 格赤木 和夫白川 英樹
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To develop optically and electrically anisotropic materials, we synthesized poly(thienylene) derivatives with liquid crystalline substituents at the 3-position of thiophene ring. Polythiophene derivatives were synthesized with Ni(0) catalyst, while polythienylenevinylene derivatives were synthesized with Heck reaction following Stille reaction. All polymers showed liquid crystalline phases in cooling process. The oriented film of the polymer exhibited an anisotropic fluorescence.
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© 1997 一般社団法人日本液晶学会
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