2003 Volume 71 Issue 12 Pages 1064-1066
The Ag-Sn system has been studied as a promising alternative anode material for advanced Li-ion batteries. Some electrodes with suitable composition and nanostructure exhibit excellent cycleability, being capable of maintaining a reversible capacity of ∼200 mAh/g over 300 cycles. The study reveals that the substantially enhanced cycling performance of these anode materials can be attributed to nanosized microstructure, uniform distribution of structurally stable compound Ag3Sn in Sn matrix as well as suitable Ag3Sn/Sn ratio.