2004 Volume 72 Issue 12 Pages 833-835
The polarized potential window (ppw) of 450 mV is available at the interface between water (W) and the room-temperature molten salt (RTMS) that consists of tetraoctylammonium cations and trifluoromethylsulfonylnonafluoro-butylsulfonylimide anions. The ppw at the interface between W and RTMS made of several combinations of hydrophobic cations and anions is correlated with the standard ion-transfer potentials of the ions at the 1,2-dichloroethane | W interface. This correlation is useful not only to predict the width of the ppw but also to approximately estimate the point of zero charge at the RTMS | W interface.