Electrochemistry
Online ISSN : 2186-2451
Print ISSN : 1344-3542
ISSN-L : 1344-3542
Comprehensive Papers
Cyclic Voltammetry Part 1: Fundamentals
Hirohisa YAMADA Kazuki YOSHIIMasafumi ASAHIMasanobu CHIKUYuki KITAZUMI
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2022 Volume 90 Issue 10 Pages 102005

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Abstract

“Cyclic voltammetry” is one of the most common electrochemical techniques, not only for electrochemists but also for researchers in other fields. However, the principles of cyclic voltammetry are very complex; beginners and even experts may struggle with their application. Therefore, we explain the fundamental principles in Part 1 and introduce the practical issues associated with recent trends such as fuel cells, capacitors, and sensors in Part 2. In this comprehensive paper, we focus on the electrochemical reversibility in cyclic voltammograms classified as reversible, quasi-reversible, and irreversible processes, which are useful for obtaining information on the reaction rates of electrodes. We also explain the relevant basic principles, experimental setup, and ideas of background current.

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© The Author(s) 2022. Published by ECSJ.

This is an open access article distributed under the terms of the Creative Commons Attribution 4.0 License (CC BY, http://creativecommons.org/licenses/by/4.0/), which permits unrestricted reuse of the work in any medium provided the original work is properly cited. [DOI: 10.5796/electrochemistry.22-66082].
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