繊維学会誌
Online ISSN : 1884-2259
Print ISSN : 0037-9875
一般報文
コアーシェル型複合微粒子を用いた耐衝撃アクリル樹脂の調製と物性
大松 一喜杉本 英樹仲西 英二赤坂 哲司猪俣 克弘
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2007 年 63 巻 11 号 p. 247-251

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PMMA is used as the most popular dental resin and show high strength and transparency, but is weak against an impact. Although introduction of rubber domain into a matrix polymer has been widely investigated to improve the impact resistance, strength and surface hardness of materials are decreased by rubber element. Therefore, in this study, the core-shell composite nanoparticles containing silica particles in rubber domain were prepared by emulsion polymerization with methyl methacrylate (MMA) and ethyl acrylate. These particles were added to MMA and bulk polymerization was carried out to obtain test specimen. The physical properties including impact resistance were evaluated by three-point bending test, falling ball impact test and Vicker's hardness test. The impact resistance of test specimen was improved in comparison with the test specimen prepared with core-shell particles without silica particle. Moreover, deterioration in mechanical properties was depressed by addition of silica particle to rubber element.
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© 2007 The Society of Fiber Science and Technology, Japan
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