繊維学会誌
Online ISSN : 1884-2259
Print ISSN : 0037-9875
ε-カプロラクトンとε-カプロラクタムまたはω-ラウロラクタムとの共重合体の生分解性の評価
中山 敦好川崎 典起相羽 誠一山本 襄酒井 博山崎 京子前田 育克竹内 照文東 孝
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1997 年 53 巻 9 号 p. 373-380

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Biodegradability of poly (ε-caprolactone-co-ε-caprolactam) s and poly (ε-caprolactone-co-ω-laurolactam)s was evaluated by enzymatic hydrolysis test, activated sludge test and sea-water test. The enzymes used for hydrolysis test were lipases from Rhizopus arrhizus, Rhizopus delemar, Candida cylindracea and Pseudomonas Fluorecence. The activated sludge test was conducted mainly by a modified ASTM (American Society for Testing and Materials) method. The biodegradability was evaluated with the amount of evoluved CO2. The results were similar to those by JIS (Japanese Industrial Standard) method based on BOD (Biochemical Oxygen Demand). The sea-water test carried out in a marine environment, at Kushimoto bay. Most of copolyesteramides were completely degraded for 3 months. The poly (ε-caprolactone-co-ε-caprolactam)s were degraded by the enzymatic hydrolysis test, the activated sludge test and the sea-water test. On the contrary, the poly (ε-caprolactone-co-ω-laurolactam)s were degraded by activated sludge test and sea-water test, however the enzymatic hydrolysis test showed negative results.
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