日本ゴム協会誌
Print ISSN : 0029-022X
総説
環状部位を架橋剤に用いる可動性架橋高分子
久保 雅敬
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ジャーナル フリー

2014 年 87 巻 3 号 p. 103-106

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抄録
Polymerization of a monomer in the presence of cyclic macromonomer in high concentration leads mechanically linked three-dimensional network polymer. The network structure is formed by the threading of the cyclic moiety by a segment of another polymer chain during the copolymerization process. This class of materials has attracted a great deal of interest as new functional materials with unusual chemical, physical and mechanical properties due to the high degrees of freedom in segmental movement since cross-linking points can move in these three-dimensional structures.
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