日本ゴム協会誌
Print ISSN : 0029-022X
特論講座
ナノフィラー充塡架橋ゴムにおけるナノフィラーの構造と物性
第2講 架橋ゴム中のカーボンブラックネットワークの可視化と電気特性との相関
加藤 淳池田 裕子
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2014 年 87 巻 6 号 p. 252-258

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Advantages of 3D-TEM/electron tomography are described for development of rubber science and technology. The first result of visualization of carbon black (CB) network is shown, which was obtained by combining 3D TEM/electron tomography and electric characteristic measurements. A novel analysis for characterization of the CB network is proposed on the basis of gelation mechanism of polymer network, where structural parameters of crosslined and branched chains of CB aggregates are determined by 3D-TEM/electron tomography and are utilized. Good relationships between the CB network structures and electrolytic properties are also shown in this review paper.
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