有機金属化学の基礎から最近の進歩まで

第2回　有機遷移金属錯体の基本的反応1（配位と解離， 酸化的付加と還元的脱離）

抄録

Fundamental organometallic reactions such as dissociative and associative ligand exchange processes, oxidative addition and reductive elimination are described. Importance of both steric and electronic effects of ligands on kinetic and thermodynamic stability of the metal-ligand bond is shown. Formality, mechanistic aspects, and trends of oxidative addition and reductive elimination involving bond cleavage and formation at transition metals are also described as important fundamental organometallic reactions.