NIPPON GOMU KYOKAISHI
Print ISSN : 0029-022X
THE EFFECT OF ε-CAPROLACTAM ON RUBBERS
(PART-3) THE EFFECT OF CATALYSTS ON THE GRAFTPOLYMERIZATION OFε-CAPROLACTAM ON CARBOXYUC RUBBER
S. MizunumaS. MaedaT. ShirakamiY. MinouraK. Zako
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JOURNAL FREE ACCESS

1966 Volume 39 Issue 6 Pages 435-440

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Abstract
The effect of following catalysts on the graftpolymerization of ε-caprolactam onto carboxylic polybutadiene rubber was studied. The used catalysts were phosphoric acid, benzoic acid, triethanolamine and stannous chloride dihydrate.
Although all agents showed catalytic action, phosphoric acid and triethanolamine were the most effective among these agents.
Even base triethanolamine affected as a catalyst in an acidic polymer, on the other hand, the effect of the benzoic acid and stannous chloride dihydrate were inferior to the two formers.
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© The Society of Rubber Industry, Japan
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