研究論文
熱再生型燃料電池に用いるシクロヘキサン液相脱水素触媒の研究―炭素担持貴金属触媒によるシクロヘキサン類液相脱水素反応―
1992 年 17 巻 3 号 p. 16-23
詳細
1992 年 17 巻 3 号 p. 16-23
Liquid-phase dehydrogenation of cyclohexanes with suspended noble metal catalysts yielded aromatic hydrocarbons and molecular hydrogen exclusively under boiling and refluxing conditions. Retardation effects of aromatic addends, fit well to a Langmuir-type rate equation, were especially large for those which exhibited facile simultaneous hydrogen transfer. The catalysts suitable to the benzene-hydrogenation electrode and to the endothermic dehydrogenation reactor are essentially important in the newly-proposed thermo-regenerative fuel cell system.
