抄録
It is well known that p-tert-butylthiacalixarenes can make host-guest complexation with organic guest molecules and metal cations. In order to study crystal structural properties of the host molecule with organic compounds, we tried to make a new crystal of the p-tert-butylthiacalix [6] arene with benzylamine. Treatment of thiacalix [6] arene with excess of benzylamine afforded the complex of thiacalix [6] arene with 8 molecules of benzylamine as crystals, which shows highly-extensive hydrogen bonded between host and guests to give rise to supramolecular assembly. The structure of thiacalix [6] arene as a host is 1, 2, 3-alternate with 4 molecules benzylamine as inner guests and the other 4 molecules of benzylamine locate outside of thiacalix [6] arene.
