2023 年 63 巻 2 号 p. 261-270
The mineral phase composition and structure of sintered ore are closely related to its quality. Analyzing the characteristics of the phase structure of sintered ores and studying the influence of sintering conditions are important to optimize their quality. In this study, the mineralization characteristics of ore during the sintering process were studied through interrupted quenching experiments. The results clarified the evolution of the structure of the sintered ore phases during the heating and cooling and its mechanism. In this study, the effects of the cooling rate on the mineral composition and structure of sintered ore were also studied. The results showed that the structure of the mineral phase changed during the iron ore sintering process as follows: granular → molten → dissolution texture. During the cooling process, as the temperature decreased, the magnetite and liquid phase contents gradually decreased, and the silico-ferrite of calcium and aluminum (SFCA) and hematite contents increased; however, the porosity did not change to a great extent. The formation of SFCA during the cooling stage consumed hematite and magnetite, and SFCA preferentially formed and grew on magnetite. As the cooling rate of the sinter was increased, the magnetite and silicate contents increased, and the hematite and SFCA contents decreased. Meanwhile, the structure of SFCA changed from block-like to columnar and acicular, and the aspect ratio increased.
