1963 年 5 巻 7 号 p. 581-586
The effects of the fourth elements on the alloy have been investigated in order to improve the mechanical properties and the corrosion resistance of Zr-Cu-Mo alloys at high temperature and high pressure of CO2.
Results obtained are summarized as follow: (1) Nb and Bi are excellent as the fourth element of alloying. (2) The desirable good properties are found in these alloys of Zr-0.5% Cu-1.0% Mo-1.0% Nb and Zr-0.5% Cu-1.5% Mo-1.0% Bi. (3) These alloys have better mechanical properties than ternary alloys and also these properties are much more improved by the heat-treatment. (4) These alloys have the good corrosion resistance in high temperature and pressure of CO2 in both cases of as annealed and after heat-treated state. No break away phenomenon is occurred after 2, 000 hr reaction with CO2 under pressure of 20 Kg/cm2 at 450°C.