Journal of Biorheology
Online ISSN : 1867-0474
Print ISSN : 1867-0466
Brief Communication
Orientation transition of defective lyotropic triblock copolymer lamellar phase
Shuji FujiiYuuki Yamamoto
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2014 Volume 28 Issue 1 Pages 55-60

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Abstract
We study concentration dependence of the critical shear rate of a layer orientation transition in lyotropic triblock copolymer lamellar phase. Theory predicts that suppression of undulation fluctuation by shear triggers the transition. The critical shear rate at high polymer concentration is in reasonable agreement with theory. However, experimental results at low polymer concentrations show different behavior from the prediction. Violation of the theory is attributed to defective nature of the lamellar phase, in which creation of defects prevents the suppression of the undulation fluctuation.
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© 2014 Japanese Society of Biorheology
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