JOURNAL OF CHEMICAL ENGINEERING OF JAPAN
Online ISSN : 1881-1299
Print ISSN : 0021-9592
Environment
Immobilizing TiO2 Allows H2O2 to be Present at the Start and Enhances the Photodegradation of Acid Yellow 36 (AY-36)
Nditange ShigwedhaZhaozhe HuaJian Chen
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2006 年 39 巻 4 号 p. 475-480

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The metallic semiconductor of TiO2 was immobilized in thin-film during UV photodegradation of AY-36. Immobilizing the catalyst allowed H2O2 to be present at the start of photodegradation without fear of recombination, electron band competition, and destruction of immobilized photocatalyst. The photodegradation of AY-36 was improved by 90%. Decolorization in the present method was begun more slowly but by 75 min, no difference was observed. An enzymatic method has been conducted to accurately measure the formation of extra-H2O2 concentration and its decomposition. The pH needed no adjustments; it increased slightly instead of decreasing as was seen in the previously tried AOP methods. This method has the potential of both increasing degradation and slightly reducing costs in practice.
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© 2006 The Society of Chemical Engineers, Japan
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