JOURNAL OF CHEMICAL ENGINEERING OF JAPAN
Online ISSN : 1881-1299
Print ISSN : 0021-9592
Energy
Carbonization of Cellulose Using the Hydrothermal Method
Seiichi InoueSeiji UnoTomoaki Minowa
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ジャーナル 認証あり

2008 年 41 巻 3 号 p. 210-215

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Cellulose was treated at 423–623 K under hydrothermal conditions without a catalyst to produce charcoal. The charcoal generated under hydrothermal conditions was mainly analyzed by FT-IR in order to investigate changes in its chemical structures occurring during the carbonization process. Increasing reaction temperatures decreased charcoal yield, increased its carbon-to-oxygen ratio, and promoted cellulose carbonization. Furthermore, increasing reaction temperature during hydrothermal treatment of cellulose weakened FT-IR peaks from –OH and –CH groups, showing that dehydrogenation and deoxygenation had occurred. These studies confirmed that hydrothermal conditions promoted carbonization of cellulose.
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© 2008 The Society of Chemical Engineers, Japan
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