Subcritical Water Assisted Clean Cross-Aldol Reactions

Pengyu WANG; Kazuya KOBIRO

doi:10.1252/jcej.10we308

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Subcritical Water Assisted Clean Cross-Aldol Reactions

Pengyu WANG, Kazuya KOBIRO

著者情報

キーワード: Subcritical Water, Clean Cross-Aldol Reaction, Benzaldehyde/Acetone, Acetophenone/1,3,5-trioxane, ZnCl₂

ジャーナルフリー早期公開

論文ID: 10we308

DOI https://doi.org/10.1252/jcej.10we308

この記事には本公開記事があります。

The final version of this article is now available: Vol. 44 (2011) , No. 8 p.577

詳細

抄録

Subcritical water was applied for cross-aldol reactions containing both organic materials, benzaldehyde/acetone and acetophenone/1,3,5-trioxane, and inorganic material, ZnCl₂. The results were compared to those under solvent-free conditions. Water suppressed the loss of organic materials and accelerated the formation of cross-aldol reaction products. Satisfactory yields (46-63%) were obtained with ZnCl₂.

責任著者(Corresponding author)

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