MASS TRANSFER IN A LARGE BUBBLE COLUMN

抄録

Values of the liquid-phase volumetric coefficient of mass transfer k_La in a large bubble column, 550 cm in diameter and 700 cm in liquid depth, were obtained from experimental data for carbon dioxide desorption from water, on the assumptions of perfect mixing in the liquid phase and piston flow or perfect mixing in the gas phase.
The liquid-phase mass transfer coefficient k_L was separated from k_La, using the data¹⁰⁾ on gas holdup and the bubble diameter obtained with the same column. Values of k_La were in good agreement with a previous correlation¹⁾ based on data with small bubble columns, provided that perfect mixing was assumed for both gas and liquid phases. Values of k_L ranged from 0.01 to 0.05 cm per second and were not affected appreciably by column size. The relationship between k_L and bubble diameter was roughly similar to that in small columns, although bubbles in the present experiments were somewhat larger than in small columns.