JOURNAL OF CHEMICAL ENGINEERING OF JAPAN
Online ISSN : 1881-1299
Print ISSN : 0021-9592
CALCULATION OF SOLID-LIQUID EQUILIBRIA USING THE MODIFIED BWR EQUATION OF STATE OF LEE AND KESLER
HIROKATSU MASUOKARYOZO TAWARAYASHOZABURO SAITO
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1979 Volume 12 Issue 4 Pages 257-263

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Abstract
The solubility of solid hydrocarbons and inorganics (carbon dioxide and hydrogen sulfide) in liquid hydrocarbons was correlated using the modified BWR equation of state of Lee and Kesler and the pseudocritical method to compute the fugacity coefficient of the solute in subcooled liquid. This method requires two binary parameters, k12 and s12, for each binary pair to be computed from experimental solid-liquid equilibrium data. These parameters are tabulated for a large number of binary systems. The correlation resulting from this investigation will be valuable in the design of cryogenic processes.
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© The Society of Chemical Engineers, Japan
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