JOURNAL OF CHEMICAL ENGINEERING OF JAPAN
Online ISSN : 1881-1299
Print ISSN : 0021-9592
SELF-DIFFUSIVITY AND VISCOSITY OF SIMPLE LIQUIDS
MAKOTO HARADAMASATAKA TANIGAKIAKIRA NISHIMURAWATARU EGUCHI
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ジャーナル フリー

1975 年 7 巻 6 号 p. 407-413

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抄録
A relaxation model is proposed taking both the oscillatory and dissipative modes of motion into consideration. The resultant velocity auto-correlation function is of the damped oscillatory pattern. Self-diffusivity and shear viscosity of a simple saturated liquid can be predicted from the equations derived from the model with the configurational internal energy and a parametric density which is characteristic to the substance. This density determines the probability of dissipative mode of motion. A simple relation of corresponding states holds for several liquids by employing the reduced density, which is the ratio of liquid density to the parametric density.
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© The Society of Chemical Engineers, Japan
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