Journal of the Ceramic Society of Japan
Online ISSN : 1882-1022
Print ISSN : 0914-5400
ISSN-L : 0914-5400
Synthesis of Al8B4C7 and Its Oxidation Properties in Air
Tianming WANGAkira YAMAGUCHI
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2000 Volume 108 Issue 1256 Pages 375-380

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Abstract
Al8B4C7 has been synthesized and its oxidation properties have been evaluated in both powder and sintered state. Al8B4C7 can be synthesized at above 1250°C by using Al+B4C+C as a starting material mixture. At 1800°C, no other phase could be identified. The process is achieved via gas phase. In the temperature range 700-1000°C, the results show that oxidation occurred by a parabolic kinetic process, the activation energy of the process is 25.8kJ/mol, indicating that Al8B4C7 powder is liable to oxidation. A sintered pure Al8B4C7 body cannot be satisfactorily used in air at temperatures higher than 1200°C because of its low oxidation resistance.
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