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Journal of the Ceramic Society of Japan
Vol. 125 (2017) No. 10 (October) p. 747-752

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http://doi.org/10.2109/jcersj2.17060

Feature: The 55th Symposium on Basic Science of Ceramics: Full papers

Cr-based layered double hydroxides (LDHs) containing Ni, Zn, or Cu as the divalent cation were prepared with a divalent-to-trivalent cation molar ratio of 3. Then, LDH hybrids intercalated with polyanions ([PMo12O40]3−(PMoO) or [H2W12O42]10− (HWO)) were prepared by ion exchange and hydrothermal processes. The shift of the diffraction line indicating interlayer space in the X-ray diffraction patterns confirmed the intercalation in the LDH. The fraction of PMoO and HWO anions incorporated was 30–70 or 60–90% of ion exchange capacity, respectively, by charge compensation for Cr3+. In the conversion of styrene by epoxidation and oxidation, the hybrid of the LDH composed of Zn and Cr with PMoO showed the maximum catalytic activity, with 70% conversion. For the LDH composed of Ni and Cr, hybridization with a polyanion enhanced the catalytic behavior by a synergistic effect resulting from the basicity of the LDH phase.

Copyright © 2017 The Ceramic Society of Japan

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